Syntheses of Novel Coordination Polymers Using Bis-Imidazole Ligand Having Steric Hindrance and Methoxy Group
Table 4.
Summary of crystallographic data and structure refinement parametersfor 1-3.
|
| |
1 |
2 |
3 |
|
|
| Empirical formula |
C82H120Cu2N16O18S2 |
C46H62CoN12O4S2 |
C42H56CoN10O4S2 |
|
| Formula weight |
1809.13 |
970.12 |
888.01 |
|
| Lattice |
'monoclinic' |
'monoclinic' |
'monoclinic' |
|
| a, Å |
9.9795(8) |
12.3654(5) |
9.9613(3) |
|
| b, Å |
23.2115(13) |
9.3458(3) |
23.9517(5) |
|
| c, Å |
10.0192(9) |
23.0053(9) |
10.2582(3) |
|
| α, ° |
90 |
90 |
90 |
|
| β, ° |
112.292(10) |
102.590(4) |
113.963(4) |
|
| γ, ° |
90 |
90 |
90 |
|
| V, Å3 |
2147.4(3) |
2594.67(17) |
2236.55(12) |
|
| Space group |
P21 (No. 4) |
P21/c (No. 14) |
P21/c (No. 14) |
|
| Z |
1 |
2 |
2 |
|
| ρ(calcd), g cm-3 |
1.399 |
1.242 |
1.319 |
|
| μ(MoKα), mm-1 |
0.621 |
0.463 |
0.529 |
|
| Radiateon (λ,Å) |
0.71073 |
0.71073 |
0.71073 |
|
| Temp, K |
173.15 |
173.15 |
173.15 |
|
| Reflns collected |
9762 |
6941 |
6126 |
|
| Unique reflns |
7758 |
5573 |
5340 |
|
| Param refined |
555 |
301 |
273 |
|
| R1 [I > 2σ(I)] |
0.0613 |
0.0870 |
0.0556 |
|
| wR2 [all data] |
0.1665 |
0.2345 |
0.1672 |
|
| GOF |
1.034 |
1.081 |
1.064 |
|
|
|
|
