Al-Dawaimah is an ancient Canaanite Palestinian village, occupied in 1948 by Israel, and belongs to inframediterranean to thermomediterranean thermotype and arid, semi-arid, and dry ombrotype. The study presents, a region rich in many plant vascular, and it is part of the Palestinian coast, North Africa, the Negev and the Sinai desert, in addition to the mountainous hills of Palestine located west of the Hebron, Jordan River and the Dead Sea. The objective is to identify and update the flora and vegetation in the area of Al-Dawaimah and its neighboring areas in west Hebron of Palestine. Methodology: More than 270 plant specimens have been taken from Al-Dawaimah and surroundings areas, using Braun-Blanquet, Van der Maarel and Salvador River Martinez methods to study the flora, and phytosociological plants, and 214 x 10 plants plots distributed in area were studied. Result and discussion: Three different plant communities were identified, in different environments between arid, dry- subhumid ombrotype and infra-thermomediterranean thermotype, and different soils as (carbon substrates as brown ruinsenas and terra rossa lands, limestone and others), where more than 214 species of plants have been found, of which 45 (20.02%) are endemic species, and in Raunkiaer's life system, trees represent were, (86; 40.18% trees), (34; 15.88% shrubs), (51; 23.83% chamaephytes), (10; 4.67% geophytes), (16; 7.47% phanerophytes), and (12; 6.54% hemicryptophytes). Conclusion: In Al-Dawaimah area, syntaxonomical performance of these associations are: Quercetalia ilicis Br.-Bl. ex Molinier 1934. Rhamno lycioidis-Quercion cocciferae Rivas Goday ex Rivas-Martinez 1975. 1. Rhamnus palaestinae- Quercetum calliprini ass. nova., Pistacio lentisci -Rhamnetalia alaterni Rivas-Martínez 1975. 2. Ceratonio siliquae -Pistacetum lentisci ass. nova., Junipero phoeniceae- Pinon acutisquamae A.V. Pérez et Cabezudo in A.V. Pérez et al. 1988 corr. Rivas-Martinez. et al. 2002. Pinetalia halepensis Biondi et al. 2014. 3. Junipero phoeniceae- Pinetum halepensis ass. nova.

A phytosociological review is carried out of the pine forest formations on the islands of Cuba and Hispaniola (Caribbean), due to the diversity of soils and environments. We collected 10 plant associations belonging to the class Byrsonimo-Pinetea caribaea growing on siliceous, calcareous and sandy substrates and 21 associations on special, serpentine and ophite substrates and on ultramafic rocks belonging to the class Caseario crassinervis-Pinetea cubensis, exclusive to Cuba; while the association of pine forests on serpentines in Hispaniola is included in the class Phyllantho orbicularis-Neobracetea valenzuelanae with a Caribbean distribution. The comparative phytosociological and statistical study reveals phytosociological anomalies in the inclusion of various syntaxa, and in the description of other syntaxa according to the International Code of Phytosociological Nomenclature (ICPN). We therefore propose a change in status for several of the subassociations described: subass. ilicetosum repandae: syn. var. con Ilex repanda; subass. schmidtottietosum shaferi: syn. var. with Schmidtottia shaferi; subass. acrosynanthetosum trachyphylli: syn. var. with Acrosynanthus trachyphyllus; subass. psychotrietosum grandis: var. con Psychotria grandis; subass. notodonetosum roigii: syn. var. with Notodon roigii. We also propose a nomen novum: jaquinietosum oxhyphyllae Reyes & Acosta 2012 ex Cano et al. hoc loco.

Cellulose nanofiber is an eco-friendly nanomaterial used for fabricating various functional materials. It is an alternative for synthetic plastic and other petroleum derived materials. Due to demand of CNF film, fast and rapid method for fabrication of CNF film is required. A new method on spray coating to prepare smooth cellulose nanofiber (CNF) films was developed. In this method, spraying CNF suspension onto a smooth and polished metal surface was carried out and then allowed the spray coated wet film to dry in air under standard laboratory conditions. Spraying has notable advantages such as contour coating and contactless coating with the base substrate. The basis weight and thickness of the CNF film is tailorable by adjusting CNF suspension in spraying process. CNF film prepared via spray coating has unique two-sided surface roughness with the surface in contact with the base substrate or metal side much smoother than the air-contact side. The surface roughness is one of the controlling parameter in the application of the CNF film as a substrate for flexible and printed electronics. The RMS roughness of the two surfaces investigated by Optical Profilometry [OP] was found to be 2087 nm on the rough side and 389 nm on the spray coated side, respectively. The spray coated CNF film has ultra-high smoothness on the side exposed to the polished stainless steel surface. The factors including the size of cellulose fibrils and surface smoothness of base surface that control the roughness of the film are currently being investigated and will be discussed in this chapter. The surface smoothness requirements for substrate applications in flexible and printed electronics will be discussed.

Paper is widely used in packaging applications and is biodegradable and therefore perfectly safe as green packaging wrap for the environment. The hydrophilic nature of cellulose fibrils limits the water vapour and oxygen barrier properties of paper. To mitigate these limitations, paper is often associated with other materials, such as plastics, wax and aluminum, for achieving their good barrier properties. However, these materials suffer from serious environmental issues, as difficult and inefficient to recycle. Recently, cellulose nanofibre (CNF) based materials has been considered as an alternative to produce eco-friendly barrier materials. Existing techniques to prepare cellulose nanofibre films/sheets/composites/ laminates on the paper substrates are commercially not feasible and expensive. Therefore, other cost effective and readily implementable methodologies are required to achieve cellulose nanofibre barrier layers. In the present report, a novel approach is developed using spray coating technique to produce CNF materials with excellent barrier properties. Among many coating techniques, the spray coating has many advantages such as the production of even coating surface on the base sheet and contactless coating with the substrate. A laboratory scale spray coating of cellulose nanofibre suspension on a paper substrate was developed. When the cellulose nanofibre suspension concentration was varied from 0.5 to 1.5 wt. %, coat weight is increased from 2.9±0.7 to 29.3±6.9 g/m². As a result, the air permeability of composite was decreased 0.78±0.17 to <0.0030 µm/Pa.s. Scanning electron microscopy studies of spray coated CNF laminates on the paper confirms that the surface pores in the paper substrates are filled with sprayed cellulose nanofibre and forms a continuous film on the surface of the substrate. These are the probable reasons for the reduction of air permeability of composites. A rapid preparation technique to prepare free standing cellulose nanofibre films/sheets was also developed using a bench scale spray coating system. Cellulose nanofibre suspension with concentration ranging from 1 to 2 wt% was sprayed onto a stainless steel plate, which is moving on a conveyor at a velocity of 0.32 cm/sec and then air dried. The basis weight of produced cellulose nanofibre films is varied from 52.8±7.4 to 193.1±3.4 g/m². Processing time taken to prepare films was approximately 1.0 min, which is much less than processing times reported in the previous literature. Thus, the significant reduction in preparation time for producing the cellulose nanofibre sheet recommends that this spray coating technique can be utilized for the development of a scalable process for the fabrication of various cellulose based nanocomposite. Therefore, the laboratory scale spray coating confirms that the spraying could provide a platform for development of films/sheets/nanocomposite and also a CNF barrier layer on the base sheet. The future work is the development of a continuous spray coating of cellulose nanofibre on the base sheet and evaluation of mechanical and barrier properties spray coated barrier layers on the base sheet.